Dictionary<string, System.Windows.Media.Brush> colors =
new Dictionary<string, System.Windows.Media.Brush>
{
{"Красный", System.Windows.Media.Brushes.Red},
{"Синий", System.Windows.Media.Brushes.Blue},
{"Зелёный", System.Windows.Media.Brushes.Green},
{"Жёлтый", System.Windows.Media.Brushes.Yellow},
{"Оранжевый", System.Windows.Media.Brushes.Orange},
{"Фиолетовый", System.Windows.Media.Brushes.Purple},
{"Розовый", System.Windows.Media.Brushes.Pink},
{"Чёрный", System.Windows.Media.Brushes.Black},
{"Серый", System.Windows.Media.Brushes.Gray},
{"Коричневый", System.Windows.Media.Brushes.Brown}
};
if (colors.ContainsKey(rb.Content.ToString()))
tbSample.Foreground = colors[rb.Content.ToString()];
}